博王娱乐-澳门永利赌场老板名字-海立方娱乐-威尼斯人娱乐城 老品牌值得您信赖

主講人：金國(guó)新 教授

地點(diǎn)：弘毅樓（國(guó)家重點(diǎn)實(shí)驗(yàn)室）五樓報(bào)告廳

時(shí)間：2020年10月23日（星期五）上午10:30

主講人介紹：

復(fù)旦大學(xué)特聘教授，復(fù)旦大學(xué)無(wú)機(jī)化學(xué)國(guó)家重點(diǎn)學(xué)科帶頭人。曾兼任英國(guó)皇家化學(xué)會(huì)《Dalton Transactions》副主編、美國(guó)化學(xué)會(huì)《Organometallics》、《Coordination Chemistry Review》、《Journal of Organometallic Chemistry》、《無(wú)機(jī)化學(xué)學(xué)報(bào)》和《有機(jī)化學(xué)》等刊物編委，英國(guó)皇家化學(xué)會(huì)Fellow等職。有機(jī)金屬化學(xué)國(guó)家重點(diǎn)實(shí)驗(yàn)室、稀土資源利用國(guó)家重點(diǎn)實(shí)驗(yàn)室、配位化學(xué)國(guó)家重點(diǎn)實(shí)驗(yàn)室和羰基合成與選擇氧化國(guó)家重點(diǎn)實(shí)驗(yàn)室學(xué)術(shù)委員會(huì)委員。國(guó)家自然科學(xué)基金委第九、十屆和第十二、十三屆化學(xué)評(píng)議組專(zhuān)家；1999年獲國(guó)家杰出青年基金。主要從事有機(jī)金屬配位化學(xué)、有機(jī)金屬碳硼烷化學(xué)以及有機(jī)金屬烯烴聚合催化劑的研究；已出版學(xué)術(shù)專(zhuān)著5部，發(fā)表研究論文380余篇，被引8800多次；申請(qǐng)和獲權(quán)中國(guó)發(fā)明專(zhuān)利50多項(xiàng)。2009年獲上海市自然科學(xué)一等獎(jiǎng)，2016年獲德國(guó)洪堡研究獎(jiǎng)。

主要內(nèi)容：

The construction of new inorganic and organometallic macrocycles and cages with interesting structural features and technologically useful functions have been topics of intense study with considerable potential. One of the chief motivating factors to growth in this field is the development of new, functional and tunable donor building blocks that can bridge transition metals. Ideal building blocks should be easily accessible, exhibit high affinities toward transition metals, and possess facial coordination sites can undergo exchange reactions with various ligands. Half-sandwich transition metal complexes (Cp*M, Cp* = 5-C5Me5) are useful model compounds in which one hemisphere of the coordination shell is blocked by the voluminous Cp* rings. In the protected space below the Cp* ligands, various bidentate or tridentate ligands can be accommodated. Motivated by interest in supramolecular chemistry with organometallic half-sandwich complexes, we have initiated a new approach for preparing organometallic macrocycles via C-H and B-H activations with Terephthalate and dicarboxylate carborane.2 We report herein an efficient method for synthesizing molecular macrocycles of half-sandwich iridium and rhodium complexes via C-H and B-H activation directed muticomponent self-assembly under mild condition.

主辦單位：化學(xué)與分子工程學(xué)院